esc in polycarbonate due to plasticizers

Environmental stress cracking (ESC) resistance of polycarbonate/SiO2 nanocomposites in different media - Nomai - 2017 - Journal of Applied Polymer
Polycarbonate (PC) nanocomposites containing different nano‐SiO 2 contents were prepared using a twin‐screw extruder followed by injection molding. The mechanical behavior and environmental stress cracking (ESC) resistance of the nanocomposites
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Plastic Failure through Environmental Stress Cracking
The ESC failure mechanism does not proceed through a chemical reaction between the polymer and the chemical agent. Molecular structure alteration or degradation does not occur. Significantly, in the absence of the chemical the plastic would
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The effect of plasticizers on polycarbonate structure
1/1/1987 · Effect of plastic~zers on polycarbonate structure 2073 Trm antt-plastictzmg effect or the increase in modulus of a polymer when plasticizers are introduced is, as shown in [1], more pronounced with an amorphous polycarbonate (PC) than a crystall
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ENVIRONMENTAL STRESS CRACKING – EXAMPLES FROM THE AUTOMOTIVE INDSUTRY
Environmental stress cracking (ESC) is widely regarded as the leading cause of plastic product failure. A recent study indicated that approximately 25% of plastic component failures are associated with ESC1. ESC is a failure mechanism whereby a
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Failure Analysis of Polycarbonate Chop Cover | R-TECH Materials
ESC is the premature initiation of cracking and embrittlement of plastic due to the simultaneous action of stress and strain and contact with specific substances such as sodium hydroxide. Polycarbonate is known to be particularly susceptible to
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It's the Rheo Thing: BPA is not a plasticizer
(Polymerization reactions are seldom able to achieve 100% yields due to a combination of factors, including very high viscosities reducing reactant diffusion rates.) The amount of unreacted BPA is very small, far less than 1%, and far less than
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Plasticizer
A plasticizer (UK: plasticiser) is a substance that is added to a material to make it softer and more flexible, to increase its plasticity, to decrease its viscosity, or to decrease friction during its handling in manufacture.Plasticizers are co
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Polycarbonate cracking - Polymer engineering - Eng-Tips
Polycarbonate is extremely tough as you mention. However, it is also extremely sensitive to liquids that come in contact with it and will become weakened and crack. This problem is well known and is called environmental stress cracking. It's
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Plasticizers: Types, Uses, Classification, Selection & Regulation
Super plasticizers are used for producing flowing concrete to be used in inaccessible locations, floors or where very quick placing is required. A self levelling and self-compacting concrete is called flowing concrete. Super plasticizers are als
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Environmental Stress Cracking in Polymers Q&A | Smithers
ESC is the occurrence of cracking in a polymer by contact with a liquid or vapour environment and stress. There is no chemical degradation, but the presence of the ESC agent accelerates the effect of stress by a purely physical mechanism;
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Plasticizer-Induced Stress Cracking of Rigid PVC and Polycarbonate - Medical Design Briefs
Due to rigid polycarbonate test specimen breakage, we were unable to obtain 14-day and 28-day plasticizer-induced stress cracking data on most of the polycarbonate samples. The data in Table 2 demonstrates a surprising correlation between
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ESC of polycarbonate exposed to hospital disinfectants | Request PDF
Request PDF | ESC of polycarbonate exposed to hospital disinfectants | Handheld electronic devices, including wireless phones and diagnostic devices, are used in hospital settings where they are
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A Guide to Chemical Resistance of Polycarbonate Sheet
Lexan polycarbonate sheet has a good chemical resistance, at room temperature, to a variety of dilute organic and inorganic acids. Water, vegetable oils, solutions of neutral salts, aliphatic hydrocarbons and alcohols are also included in this
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Materials: Annealing Tips for Amorphous Polymers, Part 2 | Plastics Technology
However, with polycarbonate the mixture is one of n-propanol and toluene. Parts are immersed in the mixture for a prescribed amount of time, removed and rinsed, and then evaluated for cracking. The location of any observed cracking helps to
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Polycarbonate (PC) Plastic: Properties, Uses, & Structure - Guide
28/8/2018 · Polycarbonate is a high-performance tough, amorphous and transparent thermoplastic polymer with organic functional groups linked together by carbonate groups (–O–(C=O)–O–) and offers a unique combination of properties. PC is popularly used as an
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TUFFAK polycarbonate sheet - SitefinityWebApp
as plasticizers (e.g., phthalates) or solvents, which can migrate into polycarbonate. » Resistance to paints Solvents in paints may cause stress cracking or swelling depending upon the solvent and the flash-off and drying conditions. It is
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4 Thermal Properties - Mitsubishi Engineering-Plastics corporation
4・2 Thermal Conductivity and Specific Heat As shown in Fig. 4・2‐1, the specific heat of polycarbonate changes with temperature but it can be considered that this is 1.09~1.17J/(g.k) (0.26~0.28cal/g. )for the practical temperature range.This
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Toxicity of plastics - Blastic
Due to their large molecular size, polymers are usually considered to be biochemically inert and not posing threat to environment. However, unreacted residual monomers or small oligomers can be found in the plastic material since polymerization
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Identification of polymers by IR spectroscopy. - Free Online Library
1/6/2004 · Polycarbonate Despite the presence of a carbonyl group, at 1,774 [cm.sup.-1], the strongest infrared absorptions in polycarbonate are due to the C-O single bond stretches. An intense triplet appears at 1,165, 1,194 and 1,228 [cm.sup.-1].
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